Antico, F. C., Rojas, P., Briones, F., & Araya-Letelier, G. (2021). Animal fibers as water reservoirs for internal curing of mortars and their limits caused by fiber clustering. Constr. Build. Mater., 267, 120918.
Abstract: We present a bottom-up experimental research to address evidence of internal curing of mortars using randomly distributed pig-hair as water reservoirs. Plain and reinforced mortars with pig hair ranging from 0 to 8 kg of fibers per cubic meter of mortar were prepared. The microstructures of plain and reinforced mortars were scanned using electron microscopy and the microhardnesses were measured within
the bulk cement paste and cement paste near pig fibers. Electrical resistivity, surface absorption, and residual compressive strength of mortars after freeze-thaw cycles were used to test the effects of internal curing caused by pig hair. Natural fibers used to reinforce mortars increase their toughness and provide
part of the necessary water for internal curing, yet internal curing originated by the addition of natural fibers is not proportional to fiber dosage; where the potential to form fiber clusters increases as fiber dosage increases. Results show that there is an optimum fiber dosage that maximizes internal curing
caused by these fibers. This study contributes to the research on reinforced mortars with natural fibers to provide sustainable solutions for construction materials.
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Araya-Letelier, G., Antico, F. C., Carrasco, M., Rojas, P., & Garcia-Herrera, C. M. (2017). Effectiveness of new natural fibers on damage-mechanical performance of mortar. Constr. Build. Mater., 152, 672–682.
Abstract: Addition of fibers to cement-based materials improve tensile and flexural strength, fracture toughness, abrasion resistance, delay cracking, and reduce crack widths. Natural fibers have recently become more popular in the construction materials community. This investigation addresses the characterization of a new animal fiber (pig hair), a massive food-industry waste worldwide, and its use in mortars. Morphological, physical and mechanical properties of pig hair are determined in order to be used as reinforcement in mortars. A sensitivity analysis on the volumes of fiber in mortars is developed. The results from this investigation showed that reinforced mortars significantly improve impact strength, abrasion resistance, plastic shrinkage cracking, age at cracking, and crack widths as fiber volume increases. Other properties such as compressive and flexural strength, density, porosity and modulus of elasticity of reinforced mortars are not significantly affected by the addition of pig hair. (C) 2017 Elsevier Ltd. All rights reserved.
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Guzman, D., Aguilar, C., Rojas, P., Criado, J. M., Dianez, M. J., Espinoza, R., et al. (2019). Production of Ag-ZnO powders by hot mechanochemical processing. T. Nonferr. Metal. Soc., 29(2), 365–373.
Abstract: Ag-CdO composites are still one of the most commonly used electrical contact materials in low-voltage applications owing to their excellent electrical and mechanical properties. Nevertheless, considering the restriction on using Cd due to its toxicity, it is necessary to find alternative materials that can replace these composites. In this study, the synthesis of Ag-ZnO alloys from Ag-Zn solid solutions was investigated by hot mechanochemical processing. The hot mechanochemical processing was conducted in a modified attritor mill at 138 degrees C under flowing O-2 at 1200 cm(3)/min for 3.0 h. The microstructure and phase evolution were investigated using X-ray diffractometry, field emission gun scanning electron microscopy and transmission electron microscopy. The results suggest that it is possible to complete the oxidation of Ag-Zn solid solution by hot mechanochemical processing at a low temperature and short time. This novel synthesis route can produce Ag-ZnO composites with a homogeneous distribution of nanoscale ZnO precipitates, which is impossible to achieve using the conventional material processing methods. Considering the fact that the fundamental approach to improving electric contact material performance resides in obtaining uniform dispersion of the second-phase in the Ag matrix, this new processing route could open the possibility for Ag-ZnO composites to replace non-environmentally friendly Ag-CdO.
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Guzman, D., Garcia, C., Soliz, A., Sepulveda, R., Aguilar, C., Rojas, P., et al. (2018). Synthesis and Electrochemical Properties of Ti-Si Alloys Prepared by Mechanical Alloying and Heat Treatment. Metals, 8(6), 417.
Abstract: The aim of this work was to study the synthesis and electrochemical properties of Ti 2 wt %-Si alloys prepared by mechanical alloying (MA) and heat treatment. The MA process was performed under Ar atmosphere. The structural, morphological, and compositional evolutions during the milling and subsequent heat treatment were investigated by X-ray diffraction, energy-dispersive spectroscopy, and scanning electron microscopy. The electrochemical behavior was evaluated by open circuit potential and linear sweep voltammetry measurements. The results showed that the MA process promotes the formation of a supersaturated alpha-Ti-Si solid solution. During heat treatment, the Si remaining in the mechanically alloyed powders and the Si from the alpha-Ti-Si supersaturated solid solution reacted with Ti to form Ti-Si intermetallic compounds. These compounds have a fine and homogeneous distribution in the alpha-Ti matrix, which cannot be achieved by conventional casting methods. Additionally, the electrochemical evaluations revealed that the mechanically alloyed and heat-treated Ti 2 wt %-Si powders have better corrosion resistance in 1.63 M H2SO4 than the pure Ti and MA Ti-Si samples. This is likely due to the particular microstructure produced during the milling and subsequent heat treatment.
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Jenkins, J. S., Diaz, M. R., Kurtovic, N. T., Espinoza, N., Vines, J. I., Rojas, P. A. P., et al. (2020). An ultrahot Neptune in the Neptune desert. Nat. Astron., 4(12), 1148–1157.
Abstract: About 1 out of 200 Sun-like stars has a planet with an orbital period shorter than one day: an ultrashort-period planet(1,2). All of the previously known ultrashort-period planets are either hot Jupiters, with sizes above 10 Earth radii (R-circle plus), or apparently rocky planets smaller than 2 R-circle plus. Such lack of planets of intermediate size (the `hot Neptune desert') has been interpreted as the inability of low-mass planets to retain any hydrogen/ helium (H/He) envelope in the face of strong stellar irradiation. Here we report the discovery of an ultrashort-period planet with a radius of 4.6 R-circle plus and a mass of 29 M-circle plus, firmly in the hot Neptune desert. Data from the Transiting Exoplanet Survey Satellite(3) revealed transits of the bright Sun-like star LTT 9779 every 0.79 days. The planet's mean density is similar to that of Neptune, and according to thermal evolution models, it has a H/He-rich envelope constituting 9.0(-2.9)(+2.7) % of the total mass. With an equilibrium temperature around 2,000 K, it is unclear how this `ultrahot Neptune' managed to retain such an envelope. Follow-up observations of the planet's atmosphere to better understand its origin and physical nature will be facilitated by the star's brightness (V-mag = 9.8).
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Martinez, C., Briones, F., Aguilar, C., Araya, N., Iturriza, I., Machado, I., et al. (2020). Effect of hot pressing and hot isostatic pressing on the microstructure, hardness, and wear behavior of nickel. Mater. Lett., 273, 127944.
Abstract: Nanocrystalline Ni (Ni-nc) obtained by mechanical milling may present improved mechanical properties paired with high abrasion resistance. Different sintering processes were used to consolidate Nanocrystaline Ni: hot pressed (HP) and hot-isostatic pressed (HIP). The microstructure, mechanical properties, and tribological were evaluated to compare the processes. X-ray diffraction patterns showed that HIP-consolidated specimens had larger crystallite sizes and 37% less microstrain when compared to the HP specimens. The nanohardness of the HIP specimens was also carried out and it was 50% lower than that of HP specimens, whereas its coefficient of friction found was 25% higher. These results show the advantages of the HP process over the HIP since the high pressure. The low sintering temperature of HP inhibited the grain growth, which leads excellent mechanical and tribological properties of Ni. (C) 2020 Elsevier B.V. All rights reserved.
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Martinez, C., Briones, F., Rojas, P., Aguilar, C., Guzman, D., & Ordonez, S. (2017). Microstructural and mechanical characterization of copper, nickel, and Cu-based alloys obtained by mechanical alloying and hot pressing. Mater. Lett., 209, 509–512.
Abstract: Mechanical alloying and uniaxial compaction were used to obtain configurations of: elemental powders of Cu and Ni; binary alloys (Cu-Ni and Cu-Zr); and a ternary alloy (Cu-Ni-Zr) under the same mechanical milling and hot pressing conditions. Microstructure and mechanical properties of these were investigated. According to XRD results, hot pressing process increases crystallite size and decreases microstrain in the compact samples, due to the release of crystalline defects without crystallization of amorphous alloys. The milled powder samples have a higher hardness than the unmilled samples, since crystal defects are incorporated into microstructural refinement during milling. The ternary alloy Cu-40Ni-10Zr had the highest hardness of all systems studied, reaching 689 HV0.5. Compression tests at 5% strain determined that Zr-containing samples (amorphous phase) become more fragile after processing, and have the lowest values of compressive strength. In contrast, Ni samples and Cu-Ni binary alloys are more resistant to compression. (
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Martinez, C., Briones, F., Rojas, P., Ordonez, S., Aguilar, C., & Guzman, D. (2017). Microstructure and Mechanical Properties of Copper, Nickel and Ternary Alloys Cu-Ni-Zr Obtained by Mechanical Alloying and Hot Pressing. MRS Adv., 2(50), 2831–2836.
Abstract: Elemental powders of Cu and Ni, binary alloys (Cu-Ni and Cu-Zr) and ternary alloy (Cu-Ni-Zr) obtained by mechanical alloying and uniaxial compaction hot microstructure and mechanical properties were investigated. The alloys studied were: pure Cu, pure Ni, binary alloys (Cu-Ni; Cu-Zr) and ternary alloys (Cu-Ni-Zr) under the same mechanical milling and hot pressing conditions. The samples were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM); the mechanical properties were studied by compression tests and hardness in Vickers scale (HV0.5) on polished surfaces at room temperature. According to XRD results, hot pressing process crystallite size increase and microstrain decreases in the compact samples due to the release of crystalline defects. The compacted samples have porosity of approximately 20%. The milling powder samples have a higher hardness than the unmilled samples, this because during milling crystal defects are incorporated together with the microstructural refinement. Ternary alloy is the one with the highest hardness of all systems studied, reaching 689 HV0.5. In compression tests determined a strain 5 %, Zr-containing samples become more fragile presenting the lowest values of compressive strength. In contrast, samples of Ni and Cu-Ni binary alloy are more resistant to compression.
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Psaridi, A., Bouchy, F., Lendl, M., Grieves, N., Stassun, K. G., Carmichael, T., et al. (2022). Three new brown dwarfs and a massive hot Jupiter revealed by TESS around early-type stars. Astron. Astrophys., 664, A94.
Abstract: ontext. The detection and characterization of exoplanets and brown dwarfs around massive AF-type stars is essential to investigate and constrain the impact of stellar mass on planet properties. However, such targets are still poorly explored in radial velocity (RV) surveys because they only feature a small number of stellar lines and those are usually broadened and blended by stellar rotation as well as stellar jitter. As a result, the available information about the formation and evolution of planets and brown dwarfs around hot stars is limited.
Aims. We aim to increase the sample and precisely measure the masses and eccentricities of giant planets and brown dwarfs transiting early-type stars detected by the Transiting Exoplanet Survey Satellite (TESS).
Methods. We followed bright (V < 12 mag) stars with T-eff > 6200 K that host giant companions (R > 7R(circle plus)) using ground-based photometric observations as well as high precision radial velocity measurements from the CORALIE, CHIRON, TRES, FEROS, and MINERVA-Australis spectrographs.
Results. In the context of the search for exoplanets and brown dwarfs around early-type stars, we present the discovery of three brown dwarf companions, TOI-629b, TOI-1982b, and TOI-2543b, and one massive planet, TOI-1107b. From the joint analysis of TESS and ground-based photometry in combination with high precision radial velocity measurements, we find the brown dwarfs have masses between 66 and 68 M-Jup, periods between 7.54 and 17.17 days, and radii between 0.95 and 1.11 R-Jup. The hot Jupiter TOI-1107b has an orbital period of 4.08 days, a radius of 1.30 R-Jup, and a mass of 3.35 M-Jup. As a by-product of this program, we identified four low-mass eclipsing components (TOI-288b, TOI-446b, TOI-478b, and TOI-764b).
Conclusions. Both TOI-1107b and TOI-1982b present an anomalously inflated radius with respect to the age of these systems. TOI-629 is among the hottest stars with a known transiting brown dwarf. TOI-629b and T01-1982b are among the most eccentric brown dwarfs. The massive planet and the three brown dwarfs add to the growing population of well-characterized giant planets and brown dwarfs transiting AF-type stars and they reduce the apparent paucity.
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Rojas, P. A.., Martinez, C., Aguilar, C., Briones, F., Zelaya, M. E., & Guzman, D. (2016). Characterization of phase changes during fabrication of copper alloys, crystalline and non-crystalline, prepared by mechanical alloying. Ing. Invest., 36(3), 102–109.
Abstract: The manufacture of alloys in solid state has many differences with the conventional melting (casting) process. In the case of high energy milling or mechanical alloying, phase transformations of the raw materials are promoted by a large amount of energy that is introduced by impact with the grinding medium; there is no melting, but the microstructural changes go from microstructural refinement to amorphization in solid state. This work studies the behavior of pure metals (Cu and Ni), and different binary alloys (Cu-Ni and Cu-Zr), under the same milling/mechanical alloying conditions. After high-energy milling, X ray diffraction (XRD) patterns were analyzed to determine changes in the lattice parameter and find both microstrain and crystallite sizes, which were first calculated using the Williamson-Hall (W-H) method and then compared with the transmission electron microscope (TEM) images. Calculations showed a relatively appropriate approach to observations with TEM; however, in general, TEM observations detect heterogeneities, which are not considered for the W-H method. As for results, in the set of pure metals, we show that pure nickel undergoes more microstrain deformations, and is more abrasive than copper (and copper alloys). In binary systems, there was a complete solid solution in the Cu-Ni system and a glass-forming ability for the Cu-Zr, as a function of the Zr content. Mathematical methods cannot be applied when the systems have amorphization because there are no equations representing this process during milling. A general conclusion suggests that, under the same milling conditions, results are very different due to the significant impact of the composition: nickel easily forms a solid solution, while with a higher zirconium content there is a higher degree of glass-forming ability.
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Vera, R., Araya, R., Garin, C., Ossandon, S., & Rojas, P. (2019). Study on the effect of atmospheric corrosion on mechanical properties with impact test: Carbon steel and Galvanized steel. Mater. Corros., 70(7), 1151–1161.
Abstract: The present work presents the behavior of carbon steel and galvanized steel against atmospheric corrosion after 3 years of exposure at seven locations around the region of Valparaiso, Chile. Results show a relation between corrosion rates and environmental and meteorological conditions, categorized as CX for the Quintero zone, and C3 and C2 in the remaining six zones. Corrosion rate behaviors and material toughness losses were modeled using power functions and neural networks, found to be a function of environmental exposure time. Losses were greater for carbon steel in coastal and industrial environments, reaching 70 to 80%. This effect was reduced in galvanized steel, not exceeding 15% over the same period of exposure. The relationship between corrosion rate and loss of toughness of both materials was modeled using neural networks.
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Vera, R., Bagnara, M., Henriquez, R., Munoz, L., Rojas, P., & Diaz-Gomez, A. (2023). Performance of Anticorrosive Paint Systems for Carbon Steel in the Antarctic Marine Environment. Materials, 16(16), 5713.
Abstract: This study evaluated the behavior of three paint systems exposed to the Antarctic marine environment for 45 months compared to a control of uncoated carbon steel with a determined corrosion rate. At the study site, all environmental conditions, solar radiation, and the concentration of environmental pollutants (Cl- and SO2) were evaluated. The paint systems differed in terms of the primer and top coat. Coated samples were studied before and after exposure. They were evaluated visually and using SEM to determine adhesion, abrasion, and contact angle; using the Evans X-Cut Tape Test; using ATR-FTIR spectroscopy to analyze the state of aging of the top layer; and using electrochemical impedance spectroscopy (EIS) for coat protection characterization. The corrosion rate obtained for steel was 85.64 mu m year (-1), which aligned with a C5 environmental corrosivity category. In general, the evaluation in the period studied showed the paint systems had good adhesion and resistance to delamination, without the presence of surface rust, and exhibited some loss of brightness, an increase in the abrasion index, and a decrease in the percentage of reflectance due to aging. EIS showed good protection capability of the three coating schemes. In general, this type of paint system has not previously been evaluated in an extreme environment after 45 months of exposure to the environment. The results showed that the best behavior was found for the system whose top layer was acrylic-aliphatic polyurethane.
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Vera, R., Cruz, E., Bagnara, M., Araya, R., Henriquez, R., Diaz-Gomez, A., et al. (2018). Evaluation of anticorrosive coatings on carbon steel in marine environments: Accelerated corrosion test and field exposure. Int. J. Electrochem. Sci., 13(1), 898–914.
Abstract: This study assesses the behavior of two paint systems applied to A-36 steel, commonly used to cover industrial structures in marine environments. Accelerated tests were carried out in a salt spray chamber with a maximum of 3000 hours of exposure, while other tests were conducted in the field in five areas in Chile over a period of two years. Coatings were assessed with measurements of thickness, adherence, and blistering. The behaviors of these coatings were assessed using electrochemical impedance spectroscopy (EIS techniques, measuring the evolution of an impedance module at 0.1 Hz. The results show that, after two years of exposure or after 3000 hours in the salt spray chamber, the two coatings still present adequate protective properties, with an impedance module value log vertical bar Z vertical bar greater than 10(6) Omega cm(2). However, for all tests, comparing C5MB and C5IB coating systems, the latter is always less protective for the steel.
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Vera, R., Valverde, B., Olave, E., Diaz-Gomez, A., Sanchez-Gonzalez, R., Munoz, L., et al. (2022). Corrosion Behavior of Copper Exposed in Marine Tropical Atmosphere in Rapa Nui (Easter Island) Chile 20 Years after MICAT. Metals, 12(12), 2082.
Abstract: Atmospheric corrosion of copper, exposed on a tropical island in the South-Central Pacific Ocean, was reported and compared with those of a very similar study at the same site conducted 20 years earlier. The new measurements-taken over three years of exposure, from 2010 to 2013-quantified corrosion by mass loss, characterized corrosion products by X-ray diffraction (DRX) and Raman techniques, observed the attack morphology by Scanning Electron Microscope (SEM), and evaluated the patina resistance using electrochemical techniques. The results showed a copper corrosivity category of C4, and the main copper patina compound, cuprite, was porous, nonhomogeneous, and thin. Electrochemical measurements showed cuprite layer growth as a function of the exposure time, and the morphology did not favor corrosion protection. Finally, when comparing the results to those of a study 22 years previous, the copper corrosion rates increased only slightly, even with increased contaminants associated with growing local populations and continuous tourism on the island.
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Vera, R., Valverde, B., Olave, E., Sanchez, R., Diaz-Gomez, A., Munoz, L., et al. (2023). Atmospheric corrosion and impact toughness of steels: Case study in steels with and without galvanizing, exposed for 3 years in Rapa Nui Island. Heliyon, 9(7), e17811.
Abstract: We studied atmospheric corrosion on Rapa Nui Island, using galvanized and non-galvanized SAE 1020 steel samples exposed on racks. We also added Charpy samples of both materials to directly determine the effect of corrosion rate on these materials' impact toughness. The results indicated a correlation between corrosion rate and toughness loss in the studied materials. In the corrosion study, we could also demonstrate the effect from increased insular population growth on con-taminants which aid atmospheric corrosivity. Results showed that atmospheric SO2 has tripled compared with similar corrosion studies done 20 years ago (Mapa Iberoamericano de Corrosi & PRIME;on, MICAT), increasing corrosion rates. Our results show how human factors can influence changes in environmental variables that strengthen corrosion.
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