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Ahrer, E. M., Alderson, L., Batalha, N. M., Batalha, N. E., Bean, J. L., Beatty, T. G., et al. (2023). Identification of carbon dioxide in an exoplanet atmosphere. Nature, Early Access.
Abstract: Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (that is, elements heavier than helium, also called 'metallicity')(1-3), and thus the formation processes of the primary atmospheres of hot gas giants(4-6). It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets(7-9). Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification(10-12). Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme(13,14). The data used in this study span 3.0-5.5micrometres in wavelength and show a prominent CO2 absorption feature at 4.3micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0micrometres that is not reproduced by these models.
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Aledo, J. A., Goles, E., Montalva-Medel, M., Montealegre, P., & Valverde, J. C. (2023). Symmetrizable Boolean networks. Inf. Sci., 626, 787–804.
Abstract: In this work, we provide a procedure that allows us to transform certain kinds of deterministic Boolean networks on minterm or maxterm functions into symmetric ones, so inferring that such symmetrizable networks can present only periodic points of periods 1 or 2. In particular, we deal with generalized parallel (or synchronous) dynamical systems (GPDS) over undirected graphs, i. e., discrete parallel dynamical systems over undirected graphs where some of the self-loops may not appear. We also study the class of anti-symmetric GPDS (which are non-symmetrizable), proving that their periodic orbits have period 4. In addition, we introduce a class of non-symmetrizable systems which admit periodic orbits with arbitrary large periods.
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Arulraj, A., Murugesan, P. K., Rajkumar, C., Zamorano, A. T., & Mangalaraja, R. V. (2023). Nanoarchitectonics of Layered Metal Chalcogenides-Based Ternary Electrocatalyst for Water Splitting. Energies, 16(4), 1669.
Abstract: The research on renewable energy is actively looking into electrocatalysts based on transition metal chalcogenides because nanostructured electrocatalysts support the higher intrinsic activity for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). A major technique for facilitating the conversion of renewable and sustainable energy is electrochemical water splitting. The aim of the review is to discuss the revelations made when trying to alter the internal and external nanoarchitectures of chalcogenides-based electrocatalysts to enhance their performance. To begin, a general explanation of the water-splitting reaction is given to clarify the key factors in determining the catalytic performance of nanostructured chalcogenides-based electrocatalysts. To delve into the many ways being employed to improve the HER's electrocatalytic performance, the general fabrication processes utilized to generate the chalcogenides-based materials are described. Similarly, to enhance the OER performance of chalcogenides-based electrocatalysts, the applied complementary techniques and the strategies involved in designing the bifunctional water-splitting electrocatalysts (HER and OER) are explained. As a conclusive remark, the challenges and future perspectives of chalcogenide-based electrocatalysts in the context of water splitting are summarized.
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Aylwin, R., Henriquez, F., & Schwab, C. (2023). ReLU Neural Network Galerkin BEM. J. Sci. Comput., 95(2), 41.
Abstract: We introduce Neural Network (NN for short) approximation architectures for the numerical solution of Boundary Integral Equations (BIEs for short). We exemplify the proposed NN approach for the boundary reduction of the potential problem in two spatial dimensions. We adopt a Galerkin formulation-based method, in polygonal domains with a finite number of straight sides. Trial spaces used in the Galerkin discretization of the BIEs are built by using NNs that, in turn, employ the so-called Rectified Linear Units (ReLU) as the underlying activation function. The ReLU-NNs used to approximate the solutions to the BIEs depend nonlinearly on the parameters characterizing the NNs themselves. Consequently, the computation of a numerical solution to a BIE by means of ReLU-NNs boils down to a fine tuning of these parameters, in network training. We argue that ReLU-NNs of fixed depth and with a variable width allow us to recover well-known approximation rate results for the standard Galerkin Boundary Element Method (BEM). This observation hinges on existing well-known properties concerning the regularity of the solution of the BIEs on Lipschitz, polygonal boundaries, i.e. accounting for the effect of corner singularities, and the expressive power of ReLU-NNs over different classes of functions. We prove that shallow ReLU-NNs, i.e. networks having a fixed, moderate depth but with increasing width, can achieve optimal order algebraic convergence rates. We propose novel loss functions for NN training which are obtained using computable, local residual a posteriori error estimators with ReLU-NNs for the numerical approximation of BIEs. We find that weighted residual estimators, which are reliable without further assumptions on the quasi-uniformity of the underlying mesh, can be employed for the construction of computationally efficient loss functions for ReLU-NN training. The proposed framework allows us to leverage on state-of-the-art computational deep learning technologies such as TENSORFLOW and TPUs for the numerical solution of BIEs using ReLU-NNs. Exploratory numerical experiments validate our theoretical findings and indicate the viability of the proposed ReLU-NN Galerkin BEM approach.
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Benedikt, M., Kikot, S., Ostropolski-Nalewaja, P., & Romero, M. (2023). On Monotonic Determinacy and Rewritability for Recursive Queries and Views. ACM Trans. Comput. Log., 24(2), 16.
Abstract: A query Q is monotonically determined over a set of views V if Q can be expressed as a monotonic function of the view image. In the case of relational algebra views and queries, monotonic determinacy coincides with rewritability as a union of conjunctive queries, and it is decidable in important special cases, such as for conjunctive query views and queries. We investigate the situation for views and queries in the recursive query language Datalog. We give both positive and negative results about the ability to decide monotonic determinacy, and also about the co-incidence of monotonic determinacy with Datalog rewritability.
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Bravo, V., Hernandez, R., & Venegas, O. (2023). Two-Point Distortion Theorems for Harmonic Mappings. Bull. Malaysian Math. Sci., 46(3), 100.
Abstract: We establish two-point distortion theorems for sense-preserving planar harmonic map -pings f = h + g in the unit disk D which satisfy harmonic versions of the univalence criteria due to Becker and Nehari. In addition, we also find two-point distortion theo-rems for the cases when h is a normalized convex function and, more generally, when h(D) is a c-linearly connected domain.
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Bugedo, G., Tobar, E., Alegria, L., Oviedo, V., Arellano, D., Basoalto, R., et al. (2023). Development of mechanical ventilators in Chile. Chronicle of the initiative "Un Respiro para Chile. Rev. Med. Chile, 150(7), 958–965.
Abstract: At the beginning of the COVID-19 pandemic in Chile, in March 2020, a projection indicated that a significant group of patients with pneumonia would require admission to an Intensive Care Unit and connection to a mechanical ventilator. Therefore, a paucity of these devices and other supplies was predicted. The initiative “Un respiro para Chile” brought together many people and institutions, public and private. In the course of three months, it allowed the design and building of several ventilatory assistance devices, which could be used in critically ill patients.
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Carbonnel, C., Romero, M., & Zivny, S. (2022). The Complexity of General-Valued Constraint Satisfaction Problems Seen from the Other Side. SIAM J. Comput., 51(1), 19–69.
Abstract: The constraint satisfaction problem (CSP) is concerned with homomorphisms between two structures. For CSPs with restricted left-hand-side structures, the results of Dalmau, Languages and Programming, Springer, New York, 2007, pp. 279--290] establish the precise borderline of polynomial-time solvability (subject to complexity-theoretic assumptions) and of solvability by bounded-consistency algorithms (unconditionally) as bounded treewidth modulo homomorphic equivalence. The general-valued constraint satisfaction problem (VCSP) is a generalization of the CSP concerned with homomorphisms between two valued structures. For VCSPs with restricted left-hand-side valued structures, we establish the precise borderline of polynomial-time solvability (subject to complexity-theoretic assumptions) and of solvability by the kth level of the Sherali--Adams LP hierarchy (unconditionally). We also obtain results on related problems concerned with finding a solution and recognizing the tractable cases; the latter has an application in database theory.
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Carrasco, P., & Hernandez, R. (2023). Schwarzian derivative for convex mappings of order a. Anal. Math. Phys., 13(2), 22.
Abstract: The main purpose of this paper is to obtain sharp bounds of the norm of Schwarzian derivative for convex mappings of order alpha in terms of the value of f '' (0), in particular, when this quantity is equal to zero. In addition, we obtain sharp bounds for distortion and growth for this mappings and we generalize the results obtained by Suita (J Hokkaido Univ Ed Sect II A 46(2):113-117, 1996) and Yamashita (Hokkaido Math J 28:217-230, 1999) for this particular case.
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Chen, Y., Bo Liu, B., Luo, Y., Martinez-Villalobos, C., Guoyu Ren, G., Huang, Y., et al. (2023). Relative Contribution of Moisture Transport during TC-Active and TC-Inactive Periods to the Precipitation in Henan Province of North China: Mean State and an Extreme Event. J. Clim., 36(11), 3611–3623.
Abstract: A Lagrangian model—the Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT)—is used to quantify changes in moisture sources and paths for precipitation over North China’s Henan Province associated with tropical cyclone (TC) over the western North Pacific (WNP) during July–August of 1979–2021. During TC-active periods, an anomalous cyclone over the WNP enhances southeasterly and reduces southwesterly moisture transport to Henan. Accordingly, compared to TC-inactive periods, moisture contributions from the Pacific Ocean (PO), eastern China (EC), and the local area (Local) are significantly enhanced by 48.32% (16.73% versus 11.28%), 20.42% (9.44% versus 7.84%), and 2.89% (4.91% versus 4.77%), respectively, while moisture contributions from the Indian Ocean (IO), Southwestern China (SWC), Eurasia (EA), and the South China Sea (SCS) are significantly reduced by −31.90% (8.61% versus 12.64%), −16.27% (4.60% versus 5.50%), −8.81% (19.10% versus 20.95%), and −6.92% (12.18% versus 13.09%). Furthermore, the moisture transport for a catastrophic extreme rainfall event during 17–22 July (“21⋅7” event) influenced by Typhoon Infa is investigated. Compared to the mean state during TC-active periods, the moisture contribution from the PO was substantially increased by 126.32% (37.87% versus 16.73%), while that from IO significantly decreased by −98.26% (0.15% versus 8.61%) during the “21⋅7” event. Analyses with a bootstrap resampling method show that moisture contributions from the PO fall outside the +6σ range, for both the TC-active and TC-inactive probability distributions. Thus, the “21⋅7” event is rare and extreme in terms of the moisture contribution from the PO, with the occurrence probability being less than 1 in 1 million times.
Significance Statement
Henan, one of the most populated provinces in China, experienced a catastrophic extreme precipitation event in July 2021 (the “21⋅7” event), coinciding with the activity of a tropical cyclone (TC) over the western North Pacific, which helps establish the moisture channel. Using a Lagrangian model, we provide a better understanding of how moisture transport changes associated with TC for the mean state of 1979–2021, and reveal how extreme is the moisture transport for the “21⋅7” event with the bootstrap technique. It is found that during active TC periods, the moisture contribution from the Pacific Ocean (the Indian Ocean) is significantly enhanced (reduced). For every 1 000 000 six-day events, less than one instance like the “21⋅7” event should be expected.
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Cheng, Y. C., Watari, T., Seccatore, J., Nakajima, K., Nansai, K., & Takaoka, M. (2023). A review of gold production, mercury consumption, and emission in artisanal and small-scale gold mining (ASGM). Resour. Policy, 81, 103370.
Abstract: Artisanal and small-scale gold mining (ASGM) is one of the largest sources of Hg emissions and is critical for addressing the Hg problem. Due to scarce and punctual statistics provided by governments and agencies, there is almost no accurate data on ASGM production, Hg use, and emissions. In this study, we surveyed different ap-proaches to estimate ASGM production and collected data from different sources, including academic papers and technical reports. Globally, 380-870 tonnes of gold is produced by ASGM each year, with a median value of 520 tonnes. The Hg use in the ASGM sector was estimated to be 640-1000 tonnes each year, with a median value of 892 tonnes. Consequently, 248-838 tonnes of Hg are emitted from the ASGM sector each year, with a median value of 615 tonnes. However, significant discrepancies were found in the data calculated using different ap-proaches, particularly in countries where the estimates were large, such as China. To obtain a more accurate picture of global ASGM activities, a general estimation approach combining specific studies of dominant coun-tries is necessary. For better management of ASGM in the future, developing a solid baseline and comprehensive future projection scenarios and establishing international collaboration to construct guidance on ASGM are recommended.
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Efraimidis, I., Hernandez, R., & Martin, M. J. (2023). Ahlfors-Weill extensions for harmonic mappings. J. Math. Anal. Appl., 523(2), 127053.
Abstract: We provide two new formulas for quasiconformal extension to C for harmonic mappings defined in the unit disk and having sufficiently small Schwarzian derivative. Both are generalizations of the Ahlfors-Weill extension for holomorphic functions.(c) 2023 Elsevier Inc. All rights reserved.
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Escobar, C., Vargas, F. J., Peters, A. A., & Carvajal, G. (2023). A Cooperative Control Algorithm for Line and Predecessor Following Platoons Subject to Unreliable Distance Measurements. Mathematics, 11(4), 801.
Abstract: This paper uses a line-following approach to study the longitudinal and lateral problems in vehicle platooning. Under this setup, we assume that inter-vehicle distance sensing is unreliable and propose a cooperative control strategy to render the platoon less vulnerable to these sensing difficulties. The proposed control scheme uses the velocity of the predecessor vehicle, communicated through a Vehicle-to-Vehicle technology, to avoid significant oscillations in the local speed provoked by tracking using unreliable local distance measurements. We implement the proposed control algorithm in the RUPU platform, a low-cost experimental platform with wireless communication interfaces that enable the implementation of cooperative control schemes for mobile agent platooning. The experiments show the effectiveness of the proposed cooperative control scheme in maintaining a suitable performance even when subject to temporal distortions in local measurements, which, in the considered experimental setup, arise from losing the line-of-sight of the local sensors in paths with closed curves.
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Faouzi, T., Porcu, E., Kondrashuk, I., & Bevilacqua, M. (2023). Convergence arguments to bridge cauchy and matern covariance functions. Stat. Pap., Early Access.
Abstract: The Matern and the Generalized Cauchy families of covariance functions have a prominent role in spatial statistics as well as in a wealth of statistical applications. The Matern family is crucial to index mean-square differentiability of the associated Gaussian random field; the Cauchy family is a decoupler of the fractal dimension and Hurst effect for Gaussian random fields that are not self-similar. Our effort is devoted to prove that a scale-dependent family of covariance functions, obtained as a reparameterization of the Generalized Cauchy family, converges to a particular case of the Matern family, providing a somewhat surprising bridge between covariance models with light tails and covariance models that allow for long memory effect.
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Feinstein, A. D., Radica, M., Welbanks, L., Murray, C. A., Ohno, K., Coulombe, L. P., et al. (2023). Early Release Science of the exoplanet WASP-39b with JWST NIRISS. Nature, Early Access.
Abstract: The Saturn-mass exoplanet WASP-39b has been the subject of extensive efforts to determine its atmospheric properties using transmission spectroscopy(1-4). However, these efforts have been hampered by modelling degeneracies between composition and cloud properties that are caused by limited data quality(5-9). Here we present the transmission spectrum of WASP-39b obtained using the Single-Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument on the JWST. This spectrum spans 0.6-2.8 mu m in wavelength and shows several water-absorption bands, the potassium resonance doublet and signatures of clouds. The precision and broad wavelength coverage of NIRISS/SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favouring a heavy-element enhancement ('metallicity') of about 10-30 times the solar value, a sub-solar carbon-to-oxygen (C/O) ratio and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are also best explained by wavelength-dependent, non-grey clouds with inhomogeneous coverageof the planet's terminator.
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Ferrada, F., Babonneau, F., Homem-de-Mello, T., & Jalil-Vega, F. (2023). The role of hydrogen for deep decarbonization of energy systems: A Chilean case study. Energy Policy, 177, 113536.
Abstract: In this paper we implement a long-term multi-sectoral energy planning model to evaluate the role of green hydrogen in the energy mix of Chile, a country with a high renewable potential, under stringent emission reduction objectives in 2050. Our results show that green hydrogen is a cost-effective and environmentally friendly route especially for hard-to-abate sectors, such as interprovincial and freight transport. They also suggest a strong synergy of hydrogen with electricity generation from renewable sources. Our numerical simulations show that Chile should (i) start immediately to develop hydrogen production through electrolyzers all along the country, (ii) keep investing in wind and solar generation capacities ensuring a low cost hydrogen production and reinforce the power transmission grid to allow nodal hydrogen production, (iii) foster the use of electric mobility for cars and local buses and of hydrogen for long-haul trucks and interprovincial buses and, (iv) develop seasonal hydrogen storage and hydrogen cells to be exploited for electricity supply, especially for the most stringent emission reduction objectives.
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Gaikwad, V. M., Dash, B. B., Sahoo, P. K., Shirbhate, S. C., Pabba, D. P., Acharya, S. A., et al. (2023). Polarization induced ferroelectric and magnetic ordering in double-perovskite-based flexible 0-3 composite. J. Mater. Sci. Mater. Electron., 34(8), 720.
Abstract: The novel multiferroic flexible films of Dy2NiMnO6 (DNMO) were prepared by incorporating DNMO particles in Polyvinylidene fluoride-based co-polymeric P(VDF-HFP) system. The structural studies validated the crystalline structure of DNMO remains unaffected by the presence of polymer. The scanning electron microscopic image of the composite sample confirms the uniform distribution of DNMO particles in the polymeric matrix. The enhancement in the ferroelectric parameters was observed for the composite sample in comparison with P(VDF-HFP) polymeric film. The composite sample exhibits a large polarization and coercive field at room temperature with enhanced dielectric behavior with reduced dielectric loss. M-H curves of composite show ferromagnetic nature with small increase in coercivity at 5 K. The field- and temperature-dependent magnetic characteristics of DNMO have remained unaltered even though the engagement of P(VDF-HFP) for achieving flexibility. The simultaneous existence of ferroelectric and magnetic order in the flexible DNMO may discover its application in the field of flexible magnetoelectronics.
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Goles, E., Medina, P., Montealegre, P., & Santivanez, J. (2022). Majority networks and consensus dynamics. Chaos Solitons Fractals, 164, 112697.
Abstract: Consensus is an emergent property of many complex systems, considering this as an absolute majority phenomenon. In this work we study consensus dynamics in grids (in silicon), where individuals (the vertices) with two possible opinions (binary states) interact with the eight nearest neighbors (Moore’s neighborhood). Dynamics emerge once the majority rule drives the evolution of the system. In this work, we fully characterize the sub-neighborhoods on which the consensus may be reached or not. Given this, we study the quality of the consensus proposing two new measures, namely effectiveness and efficiency. We characterize attraction basins through the energy-like and magnetization-like functions similar to the Ising spin model.
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Goles, E., Medina, P., & Santivanez, J. (2023). Majority networks and local consensus algorithm. Sci. Rep., 13(1), 1858.
Abstract: In this paper, we study consensus behavior based on the local application of the majority consensus algorithm (a generalization of the majority rule) over four-connected bi-dimensional networks. In this context, we characterize theoretically every four-vicinity network in its capacity to reach consensus (every individual at the same opinion) for any initial configuration of binary opinions. Theoretically, we determine all regular grids with four neighbors in which consensus is reached and in which ones not. In addition, in those instances in which consensus is not reached, we characterize statistically the proportion of configurations that reach spurious fixed points from an ensemble of random initial configurations. Using numerical simulations, we also analyze two observables of the system to characterize the algorithm: (1) the quality of the achieved consensus, that is if it respects the initial majority of the network; and (2) the consensus time, measured as the average amount of steps to reach convergence.
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Gonzalez-Martin, C., Carrasco, M., & Wielandt, T. G. W. (2023). Detection of Emotions in Artworks Using a Convolutional Neural Network Trained on Non-Artistic Images: A Methodology to Reduce the Cross-Depiction Problem. Empir. Stud. Arts, Early Access.
Abstract: This research is framed within the study of automatic recognition of emotions in artworks, proposing a methodology to improve performance in detecting emotions when a network is trained with an image type different from the entry type, which is known as the cross-depiction problem. To achieve this, we used the QuickShift algorithm, which simplifies images' resources, and applied it to the Open Affective Standardized Image (OASIS) dataset as well as the WikiArt Emotion dataset. Both datasets are also unified under a binary emotional system. Subsequently, a model was trained based on a convolutional neural network using OASIS as a learning base, in order to then be applied on the WikiArt Emotion dataset. The results show an improvement in the general prediction performance when applying QuickShift (73% overall). However, we can observe that artistic style influences the results, with minimalist art being incompatible with the methodology proposed.
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