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Kalyaan, A., Pinilla, P., Krijt, S., Banzatti, A., Rosotti, G., Mulders, G. D., et al. (2023). The Effect of Dust Evolution and Traps on Inner Disk Water Enrichment. Astrophys. J., 954(1), 66.
Abstract: Substructures in protoplanetary disks can act as dust traps that shape the radial distribution of pebbles. By blocking the passage of pebbles, the presence of gaps in disks may have a profound effect on pebble delivery into the inner disk, crucial for the formation of inner planets via pebble accretion. This process can also affect the delivery of volatiles (such as H2O) and their abundance within the water snow line region (within a few au). In this study, we aim to understand what effect the presence of gaps in the outer gas disk may have on water vapor enrichment in the inner disk. Building on previous work, we employ a volatile-inclusive disk evolution model that considers an evolving ice-bearing drifting dust population, sensitive to dust traps, which loses its icy content to sublimation upon reaching the snow line. We find that the vapor abundance in the inner disk is strongly affected by the fragmentation velocity (v( f)) and turbulence, which control how intense vapor enrichment from pebble delivery is, if present, and how long it may last. Generally, for disks with low to moderate turbulence (a = 1 x 10(-3)) and a range of v( f), radial locations and gap depths (especially those of the innermost gaps) can significantly alter enrichment. Shallow inner gaps may continuously leak material from beyond it, despite the presence of additional deep outer gaps. We finally find that for realistic v( f) (=10 m s(-1)), the presence of gaps is more important than planetesimal formation beyond the snow line in regulating pebble and volatile delivery into the inner disk.
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Talreja, N., Ashfaq, M., Chauhan, D., & Mangalaraja, R. V. (2023). PVP encapsulated MXene coated on PET surface (PMP)-based photocatalytic materials: A novel photo-responsive assembly for the removal of tetracycline. Environ. Res., 233, 116439.
Abstract: Tetracycline (TC) antibiotic that is effective against wide-range micro-organisms, thereby used to control bacterial infection. The partial metabolism of TC antibiotics in humans and animals leads to the contamination of TC in the environments like water bodies. Thus, requirements to treat/remove/degrade TC antibiotics from the water bodies to control environmental pollution. In this context, this study focuses on fabricating PVP-MXenePET (PMP) based photo-responsive materials to degrade TC antibiotics from the water. Initially, MXene (Ti2CTx) was synthesized using a simple etching process from the MAX phase (Ti3AlC2). The synthesized MXene was encapsulated using PVP and cast onto the surface of PET to fabricate PMP-based photo-responsive materials. The rough surface and micron/nano-sized pores within the PMP-based photo-responsive materials might be improved the photo-degradation of TC antibiotics. The synthesized PMP-based photo-responsive materials were tested against the photo-degradation of TC antibiotics. The band gap value of the MXene and PMP-based photoresponsive materials was calculated to be -1.23 and 1.67 eV. Incorporating PVP within the MXene increased the band gap value, which might be beneficial for the photo-degradation of TC, as the minimum band gap value should be -1.23 eV or more for photocatalytic application. The highest photo-degradation of -83% was achieved using PMP-based photo-degradation at 0.1 mg/L of TC. Furthermore, -99.71% of photo-degradation of TC antibiotics was accomplished at pH -10. Therefore, the fabricated PMP-based photo-responsive materials might be next-generation devices/materials that efficiently degrade TC antibiotics from the water.
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