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Campos, J. L., Mosquera-Corral, A., del Rio, A. V., & Pedrouso, A. (2022). Sustainable Wastewater Management and Treatment. In Sustainability (Vol. 14, 9137).
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Crutchik, D., & Campos, J. L. (2021). Municipal Wastewater Reuse: Is it a Competitive Alternative to Seawater Desalination? Sustainability, 13(12), 6815.
Abstract: Water scarcity is becoming a global challenge to attempts to narrow the water demand-supply gap. To overcome this problem, it is sensible to consider alternative technologies that can exploit non-conventional water resources. The choice of such technologies should be, however, carefully analyzed, because any choice might be unfeasible from an economic point of view. In this work, a methodology to select the most appropriate non-conventional water resource, out of municipal wastewater and seawater, was proposed. Specifically, we attempted to determine which alternative provides cheaper water supply and production costs for domestic uses, depending on the wastewater treatment system used and the water plant capacity. The production of water under three scenarios was analyzed: (i) a city that has a conventional wastewater treatment plant (WWTP); (ii) a city that uses primary treatment and submarine outfalls to treat municipal wastewater; (iii) seawater desalination. The proposed methodology was tested in Chilean cities that are located in areas where water is a scarce resource. The results showed that the reuse of municipal wastewater represents a cost-competitive alternative to seawater desalination, mainly when municipal wastewater is treated in a conventional WWTP and when water flow demand is higher than 1500 m(3)/d. In contrast, seawater desalination becomes more profitable than wastewater reuse when the treatment of municipal wastewater is based on the use of submarine outfalls. This study provides a useful economic tool for promoting municipal wastewater reuse as a non-conventional water source for supplying water to cities that suffer from water scarcity in Chile and in similar areas of the world.
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Crutchik, D., Franchi, O., Caminos, L., Jeison, D., Belmonte, M., Pedrouso, A., et al. (2020). Polyhydroxyalkanoates (PHAs) Production: A Feasible Economic Option for the Treatment of Sewage Sludge in Municipal Wastewater Treatment Plants? Water, 12(4), 12 pp.
Abstract: Sludge is a by-product of municipal wastewater treatment plants (WWTPs) and its management contributes significantly to the operating costs. Large WWTPs usually have anaerobic sludge digesters to valorize sludge as methane and to reduce its mass. However, the low methane market price opens the possibility for generating other high value-added products from the organic matter in sludge, such as polyhydroxyalkanoates (PHAs). In this work, the economic feasibility of retrofitting two types of WWTPs to convert them into biofactories of crude PHAs was studied. Two cases were analyzed: (a) a large WWTP with anaerobic sludge digestion; and (b) a small WWTP where sludge is only dewatered. In a two-stage PHA-production system (biomass enrichment plus PHAs accumulation), the minimum PHAs cost would be 1.26 and 2.26 US$/kg PHA-crude for the large and small WWTPs, respectively. In a single-stage process, where a fraction of the secondary sludge (25%) is directly used to accumulate PHAs, the production costs would decrease by around 15.9% (small WWTPs) and 19.0% (large WWTPs), since capital costs associated with bioreactors decrease. Sensitivity analysis showed that the PHA/COD (Chemical Oxygen Demand) yield is the most crucial parameter affecting the production costs. The energy, methane, and sludge management prices also have an essential effect on the production costs, and their effect depends on the WWTP's size.
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Crutchik, D., Frison, N., Eusebi, A. L., & Fatone, F. (2018). Biorefinery of cellulosic primary sludge towards targeted Short Chain Fatty Acids, phosphorus and methane recovery. Water Res., 136, 112–119.
Abstract: Cellulose from used toilet paper is a major untapped resource embedded in municipal wastewater which recovery and valorization to valuable products can be optimized. Cellulosic primary sludge (CPS) can be separated by upstream dynamic sieving and anaerobically digested to recover methane as much as 4.02 m(3)/capita.year. On the other hand, optimal acidogenic fermenting conditions of CPS allows the production of targeted short-chain fatty acids (SCFAs) as much as 2.92 kg COD/capita . year. Here propionate content can be more than 30% and can optimize the enhanced biological phosphorus removal (EBPR) processes or the higher valuable co-polymer of polyhydroxyalkanoates (PHAs). In this work, first a full set of batch assays were used at three different temperatures (37, 55 and 70 degrees C) and three different initial pH (8, 9 and 10) to identify the best conditions for optimizing both the total SCFAs and propionate content from CPS fermentation. Then, the optimal conditions were applied in long term to a Sequencing Batch Fermentation Reactor where the highest propionate production (100-120 mg COD/g TVSfed.d) was obtained at 37 degrees C and adjusting the feeding pH at 8. This was attributed to the higher hydrolysis efficiency of the cellulosic materials (up to 44%), which increased the selective growth of Propionibacterium acidopropionici in the fermentation broth up to 34%. At the same time, around 88% of the phosphorus released during the acidogenic fermentation was recovered as much as 0.15 kg of struvite per capita . year. Finally, the potential market value was preliminary estimated for the recovered materials that can triple over the conventional scenario of biogas recovery in existing municipal wastewater treatment plants. (C) 2018 Elsevier Ltd. All rights reserved.
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